POLY (STYRENE-CO-MALEIC ANHYDRIDE) (SMA) AS A COMMERCIALLY AVAILABLE CO-POLYMER CARRYING REACTIVE ANHYDRIDE GROUPS ARE SUSCEPTIBLE BEING MODIFIED WITH DIFFERENT NUCLEOPHILIC SUBSTANCES FOR THE PREPARATION OF DIFFERENT REUSABLE HETEROGENEOUS POLYMER-SUPPORTED CATALYSTS. SINCE INTEREST IN CATALYSIS BY METAL NANOPARTICLES (NPS) IS INCREASING, THE IMMOBILIZATION OF COPPER (I) SALTS AS NPS ON HIGH SURFACE AREA SUPPORTS SUCH AS POLYMERS ALLOWS FOR HIGHER STABILITY, BETTER DISPERSION OF THE PARTICLES, AND GOOD RECYCLING PROPERTIES OF THE CATALYST. IN THE OTHER HAND, THE SYNTHESIS OF NEW SUPPORT LIKE POLYMERS FOR THE PREPARATION OF NEW REUSABLE SOLID ACID CATALYSTS IS ENVIABLE. THEREFORE, MODIFICATION OF SMA WITH 4-AMINOPYRIDINE WAS PERFORMED UNDER OPTIMIZED CONDITION. IN ORDER TO AVOID THE AGGLOMERATION TENDENCY OF NPS, COPPER IODIDE NPS WERE PREPARED IN SITU AND IMMOBILIZED ON THE MODIFIED SMA SURFACE TO GIVE THE SUPPORTED CATALYST. THIS CATALYST WAS SUCCESSFULLY EMPLOYED FOR THE ONE-POT THREE-COMPONENT CLICK SYNTHESIS OF 1, 4-DISUBSTITUTED-1H-1, 2, 3- TRIAZOLES IN GOOD YIELD. IN ADDITION, THIS MODIFIED SUPPORT WAS APPLIED IN THE SYNTHESIS OF N-SULFONIC ACID MODIFIED SMA CATALYST WHICH IS EFFICIENT IN MULTICOMPONENT SYNTHESIS OF BIOLOGICALLY ACTIVE 1, 4-DIHYDROPYRIDINE DERIVATIVES.